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Silver Catalysts Critical to Plastics Industry

 

By Samuel Etris, Senior Technical Consultant to The Silver Institute

 

The steadily growing demand for plastics is driving the increasing need for silver catalysts which are crucial to the production process.

 

Silver has long been relied upon to increase the efficiency of chemical reactions without entering into the reaction itself, and this use in the United States has been increasing at about 300,000 ounces per year over the past six years. According to the 1994 World Silver Survey, some 4 million ounces were added to the U.S. silver catalyst inventory during 1993 alone, giving a total inventory of some 12.8 million ounces in continuous use by the U.S. chemical process industry. According to The Catalyst Group, Spring House, PA, the world silver catalyst inventory is about 23 million ounces.

 

A major use of silver in the chemical industry is for ethylene oxide with more than 14 billion pounds per year produced worldwide. About 30 percent of this production is used to produce polyester fibers, audio and video tape, and molded items such as insulating handles for stoves, key tops for computers, electrical control knobs, domestic appliance components, and electrical connector housings.

 

The second major use of silver is to oxidize methyl (wood) alcohol into formaldehyde. The world production of formaldehyde, most of which is produced with silver catalysts, exceeds 15 billion pounds.

 

Formaldehyde is a prime component in hard, transparent and flame resistant thermoset resins whose uses range from laminating plywood and building beams to making plastic housings for television sets, computers, and electrical switch boxes. These products resist high temperatures, have excellent dimensional stability, and do not swell in water or in organic solvents.

 

Mixed with other chemicals, formaldehyde produces resins for the manufacture of particle board and adhesives for the building industry.

Manufacturers of silver catalysts include: Degussa/Metz Corp., South Plainfield, NJ; Du Pont Corp., Wilmington, DE; Handy & Harman, Fairfield, CT; Heraeus, Inc., Newark, NJ; Johnson Matthey, Salt Lake City, UT; Shell Oil Corp., Houston, TX; Scientific Design, Little Ferry, NJ; and Union Carbide, Charleston, WV.

Silver News - December 1994/January 1995

 
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